Acids, alkalis & the pH scale
By the end of this topic you'll know what acids, alkalis and neutral substances are, and how to use the pH scale to say how acidic or alkaline something is.
Part 1Sour, slippery, or nothing at all
Lemon juice, vinegar and fizzy drinks all taste sharp and sour. Soap and bleach feel slippery. Pure water tastes of almost nothing at all. These are not random differences — chemists sort every substance using one single scale that runs from 0 to 14.
An ACID is a family of chemicals with a pH below 7. Many of them taste sour (though you must never taste a lab chemical to find out). An ALKALI is, roughly, the chemical opposite of an acid — it has a pH above 7. A NEUTRAL substance is neither acidic nor alkaline: it sits at exactly pH 7. Pure water is the classic example.
Keywords for Part 1 — where the words come from
- Acid
- From the Latin acidus, "sour". A family of chemicals with a pH below 7 — many taste sour.
- Alkali
- From the Arabic al-qaly, "the ashes" (the first alkalis were made from plant ashes). The chemical opposite of an acid — pH above 7.
- Neutral
- From the Latin neuter, "neither". Neither acidic nor alkaline — exactly pH 7, like water.
Part 2Reading the pH scale
The pH scale runs from 0 to 14 and measures how acidic or alkaline a substance is. The rule is short and worth memorising: pH less than 7 means acid, pH exactly 7 means neutral, pH greater than 7 means alkali.
The scale also tells you how strong something is. The further from 7 a substance sits, the more corrosive it is. So a pH of 1 is a much stronger, more dangerous acid than a pH of 5. A pH of 14 is a far more corrosive alkali than a pH of 8.
Part 3Where the everyday substances sit
It helps to know which substances live at which end of the scale. The strong acids (pH 0–2) are the laboratory acids: hydrochloric acid (HCl), nitric acid (HNO₃) and sulfuric acid (H₂SO₄). The weak acids (pH 4–6) are the household and food acids: vinegar, lemon juice, fizzy drinks. Water sits at exactly pH 7. The weak alkalis (pH 8–10) include toothpaste, soap and some bleach. The one strong alkali you meet in the lab is sodium hydroxide (NaOH), at pH 12–14.
Remember that pH 7 is a single point, not a range. There is only one value that is truly neutral.
A substance has a pH of 2. What type of substance is it?
- AA weak acid
- BA strong acid
- CA neutral substance
- DA strong alkali
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Which of these is a strong (laboratory) alkali?
- Avinegar
- Bwater
- Csodium hydroxide
- Dlemon juice
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⚠ Watch out — "strong" is not the same as "concentrated"
Strong describes how far an acid or alkali sits from pH 7 — how fully it acts as an acid. Concentrated describes how much of it is dissolved in the water. They are different ideas. A more concentrated solution of the same chemical can be more corrosive, so the pH alone does not always tell you how dangerous something is.
Test yourself
7 questions · click to reveal each answer
What does the pH scale measure?
How acidic or alkaline a substance is, on a scale from 0 to 14.What pH are neutral substances, and give one example.
pH 7. Example: water.What pH range are strong acids? What pH range are strong alkalis?
Strong acids: pH 0–2. Strong alkalis: pH 12–14.Name the three laboratory acids and their formulae.
Hydrochloric acid (HCl), nitric acid (HNO₃), sulfuric acid (H₂SO₄).Which is more corrosive: pH 1 or pH 5? Explain.
pH 1. The further a substance is from 7, the more corrosive it is — and pH 1 is much further from 7 than pH 5.Acid rain has a pH of about 4. Is it a strong or weak acid? Explain.
A weak acid — pH 4 is only a little below 7, not down in the 0–2 strong range.Explain why "strong" and "concentrated" are not the same thing.
Strong is how fully a substance acts as an acid (how far from pH 7). Concentrated is how much is dissolved in the water. You can have a concentrated weak acid or a dilute strong acid.
Bases & alkalis
By the end of this topic you'll know exactly what a base is, what makes an alkali special, and why all alkalis are bases but not all bases are alkalis.
Part 1The chemicals that cancel out acids
Indigestion tablets contain a chemical that "cancels out" the acid in your stomach. Some of these acid-cancelling chemicals dissolve in water; some do not. Either way, they all do the same job — they neutralise the acid and raise its pH back towards 7.
The general word for any chemical that does this is a BASE. A base is any chemical that cancels out (neutralises) an acid, raising its pH towards 7. Metal oxides and metal carbonates are common bases.
Keywords for Part 1
- Base
- Any chemical that cancels out (neutralises) an acid, raising its pH towards 7.
- Neutralise
- From the Latin neuter, "neither". To make a solution neither acidic nor alkaline — to bring it towards pH 7.
- Soluble / insoluble
- Soluble means it can dissolve in water. Insoluble means it cannot.
Part 2An alkali is a soluble base
Here is the key idea of the whole topic. An ALKALI is simply a base that is SOLUBLE in water. That single difference matters because dissolving lets a substance do more.
Because an alkali dissolves and has a high pH, it can raise a solution's pH above 7 — it can overshoot neutral and make the solution alkaline. An insoluble base does not dissolve, so it can only cancel an acid up to pH 7 and no further. It cannot overshoot.
So the rule is: ALL alkalis are bases — but NOT all bases are alkalis. The alkalis are the special, soluble members of the larger base family.
Part 3Quick checks
What is the difference between a base and an alkali?
- AThere is no difference
- BAn alkali is a base that is soluble in water
- CA base is a soluble alkali
- DAn alkali cannot cancel out an acid
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An ammonia solution has a pH of 13. What type of chemical is it?
- AA neutral substance
- BA weak acid
- CAn alkali (soluble base)
- DAn insoluble base
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⚠ Watch out — "all bases are alkalis" is wrong
It is the other way round. All alkalis are bases, but not all bases are alkalis. Only the bases that dissolve in water (soluble bases) count as alkalis. An insoluble base, like copper oxide, is a base but never an alkali.
6-mark question — model answer
Indigestion is caused by too much stomach acid. Indigestion remedies usually contain an insoluble base, not a soluble alkali. Explain why an insoluble base is safer to use as a remedy. [6 marks]
Mark scheme — how the 6 marks are awarded
1 mark each for: base neutralises the acid; insoluble base only reaches pH 7; a soluble alkali could go beyond pH 7; an alkaline stomach is harmful / cannot overshoot. Marks are also available for clear use of the terms base, insoluble and neutralise. Maximum 6 marks.
Test yourself
7 questions · click to reveal each answer
Define 'base'.
A chemical that cancels out (neutralises) an acid, raising its pH towards 7.Define 'alkali'.
A base that is soluble in water.Are all bases alkalis? Are all alkalis bases? Explain.
No — only the soluble bases are alkalis. Yes — every alkali is a base, because it neutralises acid.What does an insoluble base do to an acid's pH? What can a soluble alkali do that it cannot?
An insoluble base raises the pH towards 7 (neutral) but not beyond. A soluble alkali can raise the pH above 7, making the solution alkaline.Give an example of an insoluble base and an example of a soluble base (alkali).
Insoluble base: copper oxide or calcium carbonate (limestone). Soluble base (alkali): sodium hydroxide or potassium hydroxide.Farmers add lime (a base) to acidic soil. Explain how this helps crops.
The base neutralises the acid in the soil, raising its pH towards neutral so that crops can grow well.A student adds excess copper oxide to acid; the solution becomes neutral, not alkaline. Explain why.
Copper oxide is an insoluble base. Because it cannot dissolve, it cannot raise the pH past 7 — so it stops at neutral instead of overshooting into alkaline.
Indicators & the colour of pH
By the end of this topic you'll know what an indicator is, what colours universal indicator shows, and how to use it to read the pH of a solution.
Part 1Telling acids and alkalis apart by colour
Imagine two clear, colourless liquids in beakers. One is a strong acid, one a strong alkali — and you must not taste or touch either, because both are corrosive. Yet a few drops of one special chemical instantly tells you which is which. That chemical is an indicator.
An INDICATOR is a chemical that changes colour depending on the pH of a solution. Digital pH probes also exist and give an exact number, but they are expensive — an indicator is quick and cheap, which is why you meet it first.
Keywords for Part 1 — where the words come from
- Indicator
- From the Latin indicare, "to point out". A chemical that points out the pH of a solution by changing colour.
- Universal
- From the Latin universalis, "the whole / all". Universal indicator shows the whole range of the pH scale, not just acid or alkali.
Part 2The universal indicator colours
Some indicators only give two colours — litmus, for example, is just red in acid and blue in alkali. Universal indicator is more useful because it shows the whole pH range, telling you not just whether a substance is an acid or an alkali but how strong it is.
Learn the colour order. At the acid end: red (strong acid) → orange → yellow (weak acid). At pH 7: green (neutral). At the alkali end: blue (weak alkali) → purple (strong alkali). The colours go red → orange → yellow → green → blue → purple as pH climbs from 0 to 14.
Part 3Reading the colour
The whole skill is to look at the colour and work backwards to the pH and the type of substance. Green means pH 7 and neutral. Red means a strong acid. Purple means a strong alkali. The green band is very narrow, because neutral is a single point (pH 7), not a range.
Universal indicator turns GREEN. What type of solution is it?
- AA strong acid
- BA weak acid
- CA neutral solution
- DA strong alkali
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Universal indicator turns PURPLE. What does this tell you?
- AIt is a weak acid
- BIt is neutral
- CIt is a strong alkali
- DIt is pure water
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⚠ Watch out — the colour belongs to the indicator
"The acid is red" is a common slip. The acid is usually colourless — it is the indicator you have added that is red. Always say "the indicator turns red in the acid", not "the acid is red". Also: only add a few drops, or you change the solution you are testing.
Test yourself
7 questions · click to reveal each answer
What is an indicator?
A chemical that changes colour depending on the pH of a solution.What colour is universal indicator in a strong acid, in a neutral solution, and in a strong alkali?
Strong acid: red. Neutral: green. Strong alkali: purple.Why is it called 'universal' indicator?
Because it shows the whole (universal) range of pH values, not just whether a substance is acid or alkali.Indicator turns yellow — classify the solution and give a possible pH.
A weak acid, about pH 5–6.Why use an indicator rather than a digital pH meter?
It is quick and cheap; meters are expensive. (A meter does give a more precise numerical pH, though.)Are the colours those of the acid, or of the indicator?
The colours of the indicator — the acid itself is usually colourless.Why is the green (neutral) band so narrow when you run the indicator across a strip from acid to alkali?
Because neutral is exactly pH 7 — a single point, not a range — so only a thin band of the strip is truly neutral and shows green.
Neutralisation & naming salts
By the end of this topic you'll know what happens when an acid meets an alkali, the word equation for it, and how to name the salt that forms.
Part 1What happens when an acid meets an alkali
Add an alkali to an acid drop by drop and the pH climbs steadily towards 7. The two cancel each other out. This is a neutralisation reaction, and the products are not dangerous at all: one is just water, and the other is a chemical called a salt.
The general word equation is one you must know by heart:
acid + alkali → salt + water
If the right amounts react, the final solution ends up neutral, at pH 7. And "salt" does not mean table salt — it is a whole family of compounds. Table salt (sodium chloride) is just the most famous one.
What are the products of a reaction between an acid and an alkali?
- Ahydrogen and water
- Ba salt and water
- Ccarbon dioxide and water
- Dtwo acids
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Part 2Naming the salt
Naming the salt looks tricky but follows two simple rules. The acid sets the ending, and the alkali (or base) sets the metal — and the metal name always comes first.
The three acids give three endings: hydrochloric acid makes a chloride, sulfuric acid makes a sulfate, and nitric acid makes a nitrate. The metal part comes from the metal in the alkali or base.
Worked example 1 — hydrochloric acid
Name the salt made when hydrochloric acid reacts with sodium hydroxide.
Worked example 2 — sulfuric acid
Name the salt made when sulfuric acid reacts with magnesium hydroxide.
Worked example 3 — nitric acid
Name the salt made when nitric acid reacts with calcium hydroxide.
⚠ Watch out — match the acid to the right ending
Mixing up the endings is the most common slip. Hydrochloric → chloride, sulfuric → sulfate, nitric → nitrate. And the salt is not "table salt" — sodium chloride is only one member of a huge family of salts.
Sulfuric acid reacts with potassium hydroxide. What is the salt called?
- Apotassium chloride
- Bpotassium sulfate
- Cpotassium nitrate
- Dpotassium hydroxide
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6-mark question — model answer
A student wants to make a sample of copper chloride. They react hydrochloric acid with copper oxide (an insoluble base). Name the products, explain how the student knows when all the acid has reacted, and describe how to get dry copper chloride. [6 marks]
Mark scheme — how the 6 marks are awarded
1 mark each for: products are salt + water / correct word equation; salt named correctly (copper chloride); add base until the acid is used up; filter off the excess base; evaporate to get dry salt. A further mark is available for clear method language. Maximum 6 marks.
Test yourself
8 questions · click to reveal each answer
What is a neutralisation reaction?
A reaction between an acid and an alkali (or base) that cancels them out, bringing the solution towards pH 7.Write the general word equation for acid + alkali.
acid + alkali → salt + water.What salt ending does each acid make — hydrochloric, sulfuric, nitric?
Hydrochloric → chloride. Sulfuric → sulfate. Nitric → nitrate.Name the salt: nitric acid + calcium hydroxide.
Calcium nitrate (+ water).Complete: sulfuric acid + barium hydroxide → ______ + water.
Barium sulfate.Where does the metal in the salt come from? Where does the ending come from?
The metal comes from the alkali (or base); the ending comes from the acid.Is table salt the only salt? Explain.
No — "salt" is a whole family of compounds. Sodium chloride (table salt) is just one of them.Predict the salt and second product: hydrochloric acid + zinc oxide.
Zinc chloride (+ water). The acid gives the chloride ending; the metal (zinc) comes from the zinc oxide base.
Reactions of acids with metals
By the end of this topic you'll know what a metal and acid make, how to name the salt, and how to test the gas with a 'squeaky pop'.
Part 1A different reaction — and a different second product
Drop a piece of magnesium into acid and it fizzes vigorously, giving off a gas. Hold a lit splint to the gas and it goes "squeaky POP!" This time, water is NOT one of the products. So what is being made?
When a metal reacts with an acid, the products are a salt and hydrogen gas. The general word equation is:
metal + acid → salt + hydrogen
An easy way to remember it is MASH: Metal + Acid → Salt + Hydrogen. The salt is named with the same rules as before — the acid sets the ending, the metal sets the metal.
What are the products when a metal reacts with an acid?
- Aa salt and water
- Ba salt and hydrogen
- Ccarbon dioxide and water
- Dan oxide and hydrogen
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Part 2Testing the gas — the squeaky pop
Fizzing tells you a gas is being made, but it does not tell you which gas — you need a test. To test for hydrogen, hold a lit splint to the gas: a high-pitched "squeaky pop" is the positive result. The pop happens because the hydrogen burns very quickly with the oxygen in the air, releasing energy in a small explosion.
Compare this with carbon dioxide, which is made when a carbonate reacts with an acid. To test for carbon dioxide, bubble the gas through limewater: it turns cloudy white. So a fizzing metal gives hydrogen (pop), while a fizzing carbonate gives carbon dioxide (cloudy limewater).
How do you test that a gas is hydrogen?
- Abubble it through limewater
- Bhold a lit splint to it — it goes 'squeaky pop'
- Csmell it
- Dsee if it turns blue
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⚠ Watch out — not every fizz is the same gas
Fizzing alone does not tell you which gas you have. A metal + acid fizzes and gives hydrogen (squeaky pop). A carbonate + acid also fizzes, but gives carbon dioxide (cloudy limewater). Always do the test — and remember that copper is too unreactive to fizz with dilute acid at all.
Test yourself
8 questions · click to reveal each answer
Write the general word equation for metal + acid.
metal + acid → salt + hydrogen.What does the mnemonic MASH stand for?
Metal + Acid → Salt + Hydrogen.Name the products: zinc + hydrochloric acid.
Zinc chloride and hydrogen.Name the products: calcium + sulfuric acid.
Calcium sulfate and hydrogen.What is the test for hydrogen, and the positive result?
Hold a lit splint to the gas — a squeaky pop shows it is hydrogen.What is the test for carbon dioxide, and the positive result?
Bubble the gas through limewater — it turns cloudy white.Why is water NOT a product of a metal + acid reaction?
The metal has no oxygen to make water — so hydrogen is given off instead.A salt is named 'iron sulfate'. Suggest the metal and acid used to make it.
The metal is iron and the acid is sulfuric acid (because sulfuric acid makes sulfates).